Solvent perturbs the reactivity of tert-butylcarbene

被引：29

作者：

Ruck, RT ^{[1
]}

Jones, M ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(98)00291-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two different sources of tert-butylcarbene are used to generate this reactive intermediate in a variety of solvents. Two products, 1,1-dimethylcyclopropane and 2-methyl-2-butene are formed. Solvents able to form an ylid or complex with the carbene strongly favor the alkene product. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2277 / 2280

页数：4