Binuclear aroyl and carbamoyl complexes of iron:: X-ray crystal structures of [Fe2(μ:σ,σ′-OCR)2(CO)5(PPh3)] (R = C6H3Me2-2,6, NiPr2)

被引：15

作者：

Anderson, S ^{[1
]}

Hill, AF ^{[1
]}

Slawin, AMZ ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 03期

关键词：

D O I：

10.1021/ic970700d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.

引用

页码：594 / +

页数：5

共 27 条

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