Preparation of styrene/methacrylic acid copolymer microspheres and their composites with metal particles

被引:35
作者
Wang, PH [1 ]
Pan, CY [1 ]
机构
[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Anhua 230026, Peoples R China
关键词
poly(styrene-co-methacrylic acid) microspheres composite particles; chemical metal deposition;
D O I
10.1007/s003960050559
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Poly(styrene-co-methacrylic acid) [P(St-co-MAA)] microspheres were prepared by emulsifier-free emulsion copolymerization of St with MAA. Fourier transform IR spectroscopy and elemental analysis were used to study the change in the content of MAA in the microspheres. The results of X-ray photoelectron spectroscopy measurements indicated the presence of carboxylic functionality on the surface of the microspheres. The P(St-co-MAA) metal composite particles were prepared by chemical metal deposition. Transmission electron microscopy observation and X-ray diffraction measurement were used to study the distribution and structure of the metal particles deposited.
引用
收藏
页码:581 / 586
页数:6
相关论文
共 22 条
[11]   COPOLYMERIZATION OF STYRENE WITH ACRYLAMIDE IN AN EMULSIFIER-FREE AQUEOUS-MEDIUM [J].
OHTSUKA, Y ;
KAWAGUCHI, H ;
SUGI, Y .
JOURNAL OF APPLIED POLYMER SCIENCE, 1981, 26 (05) :1637-1647
[12]  
OKUBO M, 1987, COLLOID POLYM SCI, V265, P1062
[13]  
Santos A. M., 1997, J APPL POLYM SCI, V65, P2343, DOI DOI 10.1002/(SICI)1097-4628
[14]   SURFACE CHARACTERIZATION OF STYRENE ACRYLAMIDE COPOLYMER LATEX-PARTICLES [J].
TAMAI, H ;
MURAKAMI, T ;
SUZAWA, T .
JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (09) :3857-3866
[15]  
Tamai H, 1996, J APPL POLYM SCI, V60, P1727
[16]   ULTRAFINE METAL PARTICLES IMMOBILIZED ON STYRENE/ACRYLIC ACID COPOLYMER PARTICLES [J].
TAMAI, H ;
HAMAMOTO, S ;
NISHIYAMA, F ;
YASUDA, H .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 171 (01) :250-253
[17]   PREPARATION AND CHARACTERISTICS OF ULTRAFINE METAL PARTICLES IMMOBILIZED ON FINE POLYMER PARTICLES [J].
TAMAI, H ;
SAKURAI, H ;
HIROTA, Y ;
NISHIYAMA, F ;
YASUDA, H .
JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 56 (04) :441-449
[18]   Preparation of styrene/acrylonitrile copolymer microspheres and their composites with metal particles [J].
Wang, PH ;
Pan, CY .
COLLOID AND POLYMER SCIENCE, 2000, 278 (03) :245-249
[19]  
WANG PH, 2000, UNPUB EUR POLYM J
[20]  
Wang YM, 1998, J APPL POLYM SCI, V70, P2307