Redox properties of free radicals

被引：76

作者：

Wayner, DDM ^{[1
]}

Houmam, A ^{[1
]}

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

ACTA CHEMICA SCANDINAVICA | 1998年 / 52卷 / 04期

关键词：

D O I：

10.3891/acta.chem.scand.52-0377

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The direct electrochemical detection of free radicals by photomodulation voltammetry is reviewed. The relationship between the measured half-wave potentials and the standard potentials, applications in thermochemical cycles and the balance between delocalization and solvation in benzylic and alkyl systems are discussed. Some new data on the redox properties of the most simple alkyl radicals, i.e. methyl, ethyl, 2-propyl and tert-butyl are presented.

引用

页码：377 / 384

页数：8

共 62 条

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