High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System

被引：116

作者：

Takahashi, Kohei ^{[1
]}

Yamashita, Makoto ^{[1
]}

Ichihara, Takeo ^{[1
]}

Nakano, Koji ^{[1
]}

Nozaki, Kyoko ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 26期

关键词：

hydroformylation; hydrogenation; linear alcohol; rhodium; ruthenium; BIPHASIC HYDROFORMYLATION; RUTHENIUM COMPLEXES; HYDROGEN-TRANSFER; CARBON-DIOXIDE; LIGANDS; RHODIUM; ALKENES; RU; PHOSPHINES; 1-HEXENE;

D O I：

10.1002/anie.201001327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical equation presented) A dual catalyst system has been developed for tandem hydroformylation/hydrogenation to produce n-undecanol from 1-decene in one pot. A combination of xantphos/[Rh(acac)(CO)2] and Shvo's catalyst (1) afforded the best results (see scheme; acac = acetylacetonate, DMA = N,N-dimethylacetamide). Polar solvents effectively suppressed the formation of undecyl formate. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA, Weinheim.

引用

页码：4488 / 4490

页数：3

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