High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects

被引：49

作者：

Boogaerts, Ine I. F. ^{[1
]}

White, Daniel F. S. ^{[2
]}

Cole-Hamilton, David J. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland

[2] Lyondell Chem Co, Newtown Sq, PA 19073 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 13期

关键词：

RHODIUM COMPLEXES; HYDROFORMYLATION;

D O I：

10.1039/b927236d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrocarbonylation of alkenes, including allyl alcohol, catalysed by rhodium complexes and wide angle bidentate ligands together with PEt(3), gives alcohols as the primary products with high chemo and regio-selectivity.

引用

页码：2194 / 2196

页数：3

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