Electrophilic α-amination of carbonyl compounds

被引：181

作者：

Erdik, E ^{[1
]}

机构：

[1] Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey

来源：

TETRAHEDRON | 2004年 / 60卷 / 40期

关键词：

electrophilic amination; enolates; alpha-amino carbonyl compounds; alpha-amino acids; chiral catalyst; chiral auxiliary;

D O I：

10.1016/j.tet.2004.07.001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrophilic amination is a valuable protocol for the regio- and stereospecific formation of C-N bonds. This review focuses on the reagents and methods for the synthesis of α-aminocarbonyl compounds using α-metallocarbonyl compounds and electrophilic nitrogen-transfer reagents.

引用

页码：8747 / 8782

页数：36

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