Energy transfer in multichromophoric self-assembled molecular squares

被引:78
作者
Würthner, F [1 ]
Sautter, A [1 ]
机构
[1] Univ Ulm, Abt Organ Chem 2, D-89081 Ulm, Germany
关键词
ELECTRON-TRANSFER; FLUORESCENT; DENDRIMERS; MACROMOLECULES; COORDINATION; COMPLEXES; LIGANDS; PD(II); PT(II); REDOX;
D O I
10.1039/b208582h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Metal-ion directed self-assembly afforded well-defined molecular squares with a mass of 12 kDa incorporating four perylene bisimide and sixteen pyrene chromophores organized in a circular way. Energy transfer from the pyrene to the perylene dye manifold is investigated by emission and excitation spectroscopy.
引用
收藏
页码:240 / 243
页数:4
相关论文
共 46 条
[1]   Light-harvesting dendrimers [J].
Adronov, A ;
Fréchet, JMJ .
CHEMICAL COMMUNICATIONS, 2000, (18) :1701-1710
[2]   Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns [J].
Balzani, V ;
Campagna, S ;
Denti, G ;
Juris, A ;
Serroni, S ;
Venturi, M .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) :26-34
[3]  
Choi MS, 2002, CHEM-EUR J, V8, P2668
[5]  
De Belder G, 2001, CHEMPHYSCHEM, V2, P49, DOI 10.1002/1439-7641(20010119)2:1<49::AID-CPHC49>3.0.CO
[6]  
2-6
[7]  
DEMAS JN, 1971, J PHYS CHEM-US, V75, P991, DOI 10.1021/j100678a001
[8]   Energy transfer in dendritic macromolecules: Molecular size effects and the role of an energy gradient [J].
Devadoss, C ;
Bharathi, P ;
Moore, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (40) :9635-9644
[9]   Self-assembly of disk-shaped molecules to coiled-coil aggregates with tunable helicity [J].
Engelkamp, H ;
Middelbeek, S ;
Nolte, RJM .
SCIENCE, 1999, 284 (5415) :785-788
[10]   Self-assembly of porphyrin arrays via coordination to transition metal bisphosphine complexes and the unique spectral properties of the product metallacyclic ensembles [J].
Fan, J ;
Whiteford, JA ;
Olenyuk, B ;
Levin, MD ;
Stang, PJ ;
Fleischer, EB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) :2741-2752