Hydrogen isotope exchange reactions involving C-H (D,T) bonds

被引：250

作者：

Junk, T ^{[1
]}

Catallo, WJ ^{[1
]}

机构：

[1] LOUISIANA STATE UNIV,LAB ECOL CHEM SVM,BATON ROUGE,LA 70803

来源：

CHEMICAL SOCIETY REVIEWS | 1997年 / 26卷 / 05期

关键词：

D O I：

10.1039/cs9972600401

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Exchange reactions involving the displacement of hydrogen bonded to carbon by its heavier isotopes are of interest for both mechanistic and product-orientated research, This review surveys practical strategies for the preparation of isotopically labelled compounds, discusses recent progress made in developing mild and regioselective exchange protocols, and summarizes the mechanistic aspects of C-H bond activation under homogeneous and heterogeneous exchange conditions.

引用

页码：401 / 406

页数：6

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