Investigations about gas phase oxygen spillover

被引：9

作者：

Baumgarten, E ^{[1
]}

Schuck, A ^{[1
]}

机构：

[1] Univ Dusseldorf, Inst Phys Chem & Elektrochem, D-40225 Dusseldorf, Germany

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 62卷 / 02期

关键词：

oxygen spillover; gas phase spillover; cake burning and spillover;

D O I：

10.1007/BF02475454

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The possible role of gas phase transport in oxygen spillover has been investigated by two methods based on different principles, viz.: 1. Comparison of CO2 formation at different temperatures (570 - 830 K) using GC; 2. Imaging experiments (burning of carbon opposite to a characteristic pattern of Pt, evaporated to glass. Both techniques clearly show that activated oxygen (probably oxygen atoms) may migrate via the gas phase and react with carbon.

引用

页码：209 / 216

页数：8

共 5 条

[1] HYDROGEN SPILLOVER THROUGH GAS-PHASE TRANSPORT OF HYDROGEN-ATOMS - REPLY [J].

BAUMGARTEN, E ;

LENTENSWAGNER, C ;

WAGNER, R .

JOURNAL OF CATALYSIS, 1990, 126 (01) :314-315

[2] FTIR INVESTIGATIONS ON THE INFLUENCE OF OXYGEN SPILLOVER ON THE OXIDATION RATE OF ADSORBED BENZOIC-ACID [J].

BAUMGARTEN, E ;

DEDEK, B .

JOURNAL OF MOLECULAR CATALYSIS, 1990, 62 (01) :37-44

[3] Investigations about coke burning and oxygen spillover [J].

Baumgarten, E ;

Schuck, A .

REACTION KINETICS AND CATALYSIS LETTERS, 1997, 61 (01) :3-12

[4]

BAUMGARTEN E, 1988, J APPL CATAL, V27, P247

[5]

BAUMGARTEN E, 1989, J CATAL, V117, P553

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