Synthesis and chemistry of 2,2'-bis-silyl-substituted 1,1'-binaphthyl derivatives

被引：13

作者：

Fabris, F ^{[1
]}

DeLucchi, O ^{[1
]}

机构：

[1] UNIV VENICE, DIPARTIMENTO CHIM, I-30123 VENICE, ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 509卷 / 01期

关键词：

silicon; silane; siloxane; silazane; disilane; 1,1-binaphthalene;

D O I：

10.1016/0022-328X(95)05791-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of hitherto unknown 1,1'-binaphthyl derivatives bearing silyl substituents at the 2,2' positions have been prepared. The 2,2'-bis(dimethylsilyl)-1,1'-binaphthale 2a is stable in the pure state, but it converts smoothly into the cyclic disiloxane 4a with water and acids or bases. The latter siloxane 4a can be converted back into the starting bishydrosilane 2a with lithium aluminium hydride.

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页码：15 / 18

页数：4

相关论文

共 35 条

[1] THE BENZOSTABASE PROTECTING GROUP FOR PRIMARY AMINES - APPLICATION TO AROMATIC-AMINES [J].

BONARLAW, RP ;

DAVIS, AP ;

DORGAN, BJ .

TETRAHEDRON LETTERS, 1990, 31 (46) :6721-6724

[2] THE BENZOSTABASE PROTECTING GROUP FOR PRIMARY AMINES - APPLICATION TO ALIPHATIC-AMINES [J].

BONARLAW, RP ;

DAVIS, AP ;

DORGAN, BJ ;

REETZ, MT ;

WEHRSIG, A .

TETRAHEDRON LETTERS, 1990, 31 (46) :6725-6728

[3]

BONARLAW RP, 1993, TETRAHEDRON, V49, P9855

[4] PREPARATION AND LITHIATION OF OPTICALLY-ACTIVE 2,2'-DIHALO-1,1'-BINAPHTHYLS - A GENERAL STRATEGY FOR OBTAINING CHIRAL, BIDENTATE LIGANDS FOR USE IN ASYMMETRIC-SYNTHESIS [J].

BROWN, KJ ;

BERRY, MS ;

WATERMAN, KC ;

LINGENFELTER, D ;

MURDOCH, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :4717-4723

[5] SYNTHESIS OF OPTICALLY-ACTIVE 2,2'-DIHALO-1,1'-BINAPHTHYLS VIA STABLE DIAZONIUM SALTS [J].

BROWN, KJ ;

BERRY, MS ;

MURDOCH, JR .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (22) :4345-4349

[6] N-BIS-SILYLATION OF ALPHA-AMINO-ACIDS - BENZOSTABASES AS AMINO PROTECTING GROUP [J].

CAVELIERFRONTIN, F ;

JACQUIER, R ;

PALADINO, J ;

VERDUCCI, J .

TETRAHEDRON, 1991, 47 (47) :9807-9822

[7] 4,5-DIHYDRO-4,4-DIMETHYL-3H-DINAPHTHO[2,1-C/1',2'-E]STANNEPIN AS A PRECURSOR OF 2,2'-BIS(LITHIOMETHYL)-1,1'-BINAPHTHYL [J].

CHONG, JM ;

MACDONALD, GK ;

PARK, SB ;

WILKINSON, SH .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (05) :1266-1268

[8] SILYLIRON CARBONYL-COMPLEXES IN ORGANIC-SYNTHESIS - SELECTIVE CONVERSION OF NITRILES INTO N,N-BIS(SILYL) ENAMINES [J].

CORRIU, RJP ;

MOREAU, JJE ;

PATAUDSAT, M .

ORGANOMETALLICS, 1985, 4 (04) :623-629

[9] ASYMMETRIC REACTIONS OF HIGH-SYMMETRY CHIRAL ORGANOSULFUR REAGENTS [J].

DELUCCHI, O .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 74 (1-4) :195-213

[10] PREPARATION OF ENANTIOMERICALLY PURE 1,1'-BINAPHTHALENE-2,2'-DIOL AND 1,1'-BINAPHTHALENE-2,2'-DITHIOL [J].

FABBRI, D ;

DELOGU, G ;

DELUCCHI, O .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (07) :1748-1750

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