A Simple Lithium(I) Salt with a Microporous Structure and Its Gas Sorption Properties

被引：88

作者：

Abrahams, Brendan F. ^{[1
]}

Grannas, Martin. J. ^{[1
]}

Hudson, Timothy A. ^{[1
]}

Robson, Richard ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 06期

基金：

澳大利亚研究理事会;

关键词：

coordination polymers; gas sorption; hydrogen; lithium; microporous materials; METAL-ORGANIC FRAMEWORK; ENHANCED HYDROGEN ADSORPTION; WALLED CARBON NANOTUBES; STORAGE;

D O I：

10.1002/anie.200906322

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Thoroughly absorbing: The simple combination of lithium ions and isonicotinate anions (1) leads to the formation of a lightweight salt (see picture; C black, O red, N blue, Li purple) that is able to reversibly sorb H2, N2, CO2, and CH4.The salt exists as a 3D network of microchannels that are occupied by solvent molecules. © 2010 Wiley-VCH Verlag GmbH & Co. KC.

引用

页码：1087 / 1089

页数：3

共 24 条

[1] Synthesis and Structural Characterization of Lithium-Based Metal-Organic Frameworks
Banerjee, Debasis
Borkowski, Lauren A.
Kim, Sun Jin
Parise, John B.
[J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (11) : 4922 - 4926
[2] Optimum conditions for adsorptive storage
Bhatia, SK
Myers, AL
[J]. LANGMUIR, 2006, 22 (04) : 1688 - 1700
[3] The potential of organic polymer-based hydrogen storage materials
Budd, Peter M.
Butler, Anna
Selbie, James
Mahmood, Khalid
McKeown, Neil B.
Ghanem, Bader
Msayib, Kadhum
Book, David
Walton, Allan
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (15) : 1802 - 1808
[4] Enhanced hydrogen adsorption on single-wall carbon nanotubes by sample reduction
Callejas, MA
Ansón, A
Benito, AM
Maser, W
Fierro, JLG
Sanjuán, ML
Martínez, MT
[J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 108 (1-2): : 120 - 123
[5] Strong H2 binding and selective gas adsorption within the microporous coordination solid Mg3(O2C-C10H6-CO2)3
Dinca, M
Long, JR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (26) : 9376 - 9377
[6] DINCA M, 2007, ANGEW CHEM, V119, P1441
[7] Observation of Cu2+-H2 interactions in a fully desolvated sodalite-type metal-organic framework
Dinca, Mircea
Han, Won Seok
Liu, Yun
Dailly, Anne
Brown, Craig M.
Long, Jeffrey R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (09) : 1419 - 1422
[8] Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]
[9] The Long Story and the Brilliant Future of Crystallized Porous Solids
Ferey, Gerard
[J]. MOLECULAR NETWORKS, 2009, 132 : 87 - 134
[10] Effect of structural and thermodynamic factors on the sorption of hydrogen by metal-organic framework compounds
Kolotilov, S. V.
Pavlishchuk, V. V.
[J]. THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2009, 45 (02) : 75 - 97

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