Synthesis and molecular structure of Bi4Ba4(μ4-O)2(μ3-OEt)8(μ-OEt)4(η2-thd)4 (Hthd equals 2,2,6,6-tetramethylheptane-3,5-dione).: An example of the formulation of a mixed-metal alkoxide assisted by dioxygen

被引：27

作者：

Parola, S

Papiernik, R

Hubert-Pfalzgraf, LG ^{[1
]}

Bois, C

机构：

[1] Univ Nice, Lab Chim Mol, URA CNRS, F-06108 Nice, France

[2] Univ Paris 06, Chim Met Transit Lab, URA CNRS, F-75230 Paris, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 05期

关键词：

D O I：

10.1039/a708052b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between bismuth ethoxide and [Ba(thd)(2)](4) (Hthd = 2,2,6,6-tetramethylheptane-3,5-dione) afforded the octanuclear Bi4Ba4(mu(4)-O)(2)(mu(3)-OEt)(8)(mu-OEt)(4)(eta(2)-thd)(4) species in high yield, the structure being determined by single-crystal X-ray diffraction; the formation of this species was precluded in anaerobic media.

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页码：737 / 739

页数：3

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