Modular cavity-tunable self-assembly of molecular bowls and crowns as structural analogues of calix[3]arenes

被引：93

作者：

Yu, SY ^{[1
]}

Huang, H

Liu, HB

Chen, ZN

Zhang, RB

Fujita, M

机构：

[1] Chinese Acad Sci, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Univ Tokyo, Dept Appl Chem, Grad Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 06期

关键词：

metallacycles; palladium; platinum; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200390190

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A [3+3] modular self-assembly gives rise to the formation of a molecular bowl or crown with syn,syn,syn conformation (see picture). These structures are analogues of calix[3]arenes and can function as anion receptors. Interestingly, an NO3- ion is found to distort from a trigonal plane into a trigonal pyramid when binding to the bottom of the molecular bowl.

引用

页码：686 / 690

页数：5

共 44 条

[1]

[Anonymous], ANGEW CHEM

[2]

[Anonymous], CALIXARENES 2001

[3]

[Anonymous], 1997, SUPRAMOLECULAR CHEM

[4]

[Anonymous], ANGEW CHEM