Investigations on metal depositions and dissolutions with an improved EQCMB based on quartz crystal impedance measurements

被引:57
作者
Bund, A [1 ]
Schwitzgebel, G [1 ]
机构
[1] Univ Saarland, Dept Chem Phys, D-66123 Saarbrucken, Germany
关键词
electrochemical quartz crystal microbalance; network analysis; damping; copper; silver;
D O I
10.1016/S0013-4686(00)00463-1
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
With the experimental set-up frequency and damping changes of resonating quartz crystals in electrochemical experiments can be measured at a time resolution of about 500 ms. The damping effects accompanying metal depositions and dissolutions (Ag and Cu) on polycrystalline Au electrodes of 6 and 10 MHz AT quartzes were studied and discussed in terms of roughness and sliding effects. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3703 / 3710
页数:8
相关论文
共 38 条
[1]   QUARTZ-CRYSTAL ELECTROGRAVIMETRY WITH CONTROLLED HYDRODYNAMICS - APPLICATIONS TO THE STUDY OF NICKEL ELECTRODEPOSITION [J].
ARKAM, C ;
BOUET, V ;
GABRIELLI, C ;
MAURIN, G ;
PERROT, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (09) :L103-L105
[2]   INFLUENCE OF THE SURFACE MICROSTRUCTURE ON THE COUPLING BETWEEN A QUARTZ OSCILLATOR AND A LIQUID [J].
BECK, R ;
PITTERMANN, U ;
WEIL, KG .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (02) :453-461
[3]   IMPROVED QUARTZ CRYSTAL MICROBALANCE TECHNIQUE [J].
BENES, E .
JOURNAL OF APPLIED PHYSICS, 1984, 56 (03) :608-626
[4]   VALIDATION OF THE QUARTZ-CRYSTAL MICROBALANCE RESPONSE IN LIQUID FOR SENSOR APPLICATIONS [J].
BOUCHEPILLON, D ;
GABRIELLI, C ;
PERROT, H .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 24 (1-3) :257-259
[5]   A NONLINEAR LEAST-SQUARES FIT PROCEDURE FOR ANALYSIS OF IMMITTANCE DATA OF ELECTROCHEMICAL SYSTEMS [J].
BOUKAMP, BA .
SOLID STATE IONICS, 1986, 20 (01) :31-44
[6]   Determination of the complex shear modulus of polymer solutions with piezoelectric resonators [J].
Bund, A ;
Chmiel, H ;
Schwitzgebel, G .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (17) :3933-3938
[7]  
BUND A, 1960, BER BUNSEN PHYS CHEM, V101, P1997
[8]   An electronic oscillator with automatic gain control: EQCM applications [J].
Chagnard, C ;
Gilbert, P ;
Watkins, AN ;
Beeler, T ;
Paul, DW .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 32 (02) :129-136
[9]   Characterization of aluminum corrosion with a quartz crystal analyzer [J].
Choi, KJ ;
Kim, YH ;
Chang, SM ;
Egawa, A ;
Muramatsu, H .
ANALYTICA CHIMICA ACTA, 1999, 386 (03) :229-236
[10]   Influence of surface roughness on the quartz crystal microbalance response in a solution - New configuration for QCM studies [J].
Daikhin, L ;
Urbakh, M .
FARADAY DISCUSSIONS, 1997, 107 :27-38