Self-inclusion in 5,11,17,23-tetra-tert-butyl-26,27,28-trihydroxy-25-(methoxycarbonylmethoxy)calix[4]-arene chloroform trisolvate

被引：10

作者：

Ben Othman, A

Cheriaa, N

Abidi, R

Vicens, J

Thuéry, P

机构：

[1] CEA Saclay, DSM DRECAM SCM, CNRS, URA 331, F-91191 Gif Sur Yvette, France

[2] ECPM, CNRS, UMR 7512, F-67087 Strasbourg 2, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104026356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, C47H60O6 . 3CHCl(3), is the first example of a lower- rim mono- ester calixarene derivative to be crystallographically characterized. The cone conformation adopted by the macrocycle is stabilized by three intramolecular hydrogen bonds. Self- inclusion of the methyl ester chain in the cavity of an adjacent molecule gives rise to infinite chains parallel to the c axis. C - H ... pi interactions involving the methyl group most imbedded in the cavity contribute to the stabilization of the system.

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页码：O859 / O861

页数：3

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