Biphosphinine rhodium and cobalt(-1) complexes

被引：35

作者：

Mézailles, N ^{[1
]}

Rosa, P ^{[1
]}

Ricard, L ^{[1
]}

Mathey, F ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7653, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 16期

关键词：

D O I：

10.1021/om000279s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 4,4′,5,5′-tetramethyl-2,2′-biphosphinine (tmbp) dianionic sodium salt 2 reacts with [M(acac)3] (M = Co, Rh) precursors to yield the anionic [M(tmbp)2]- cobalt (3, M = Co) and rhodium (4, M = Rh) complexes. Trapping of these two species with Ph3SnCl affords [M(tmbp)SnPh3] complexes (5, M = Co) and (6, M = Rh).

引用

页码：2941 / 2943

页数：3

共 24 条

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