Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies

被引：466

作者：

Takeda, Hiroyuki ^{[2
,3
]}

Ishitani, Osamu ^{[1
,3
,4
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[2] Toyota Cent Res & Dev Labs Inc, Aichi 4801192, Japan

[3] CREST JST, Tokyo, Japan

[4] SORST JST, Tokyo, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 3-4期

关键词：

Photocatalyst; CO2; reduction; Rhenium complex; Ruthenium complex; Supramolecule; VISIBLE-LIGHT IRRADIATION; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; PHOTOCHEMICAL REDUCTION; ELECTROCATALYTIC REDUCTION; PHOTOINDUCED REDUCTION; RHENIUM(I) COMPLEXES; PHOSPHORUS LIGANDS; ONE-ELECTRON; RUTHENIUM;

D O I：

10.1016/j.ccr.2009.09.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photocatalytic systems for CO2 reduction using metal complexes, especially rhenium(I) complexes as a main component, are reviewed: mononuclear Re(I) complexes, mixed systems with two different Re(I) complexes, and supramolecule systems with a Re(I) complex connected to a ruthenium(II) complex. We focus on the mechanistic studies and the architecture for constructing the photocatalytic systems based on the mechanism. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：346 / 354

页数：9

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