Preparation of (μ5-cyclopentadienyl) and (η5-methylcyclopentadienyl)Fe(CO)2Me cyclodextrin inclusion compounds and their subsequent ligand substitution reactions.: Attempts at cyclodextrin mediated enantioselective ligand substitution

被引：26

作者：

Patel, PP ^{[1
]}

Welker, ME ^{[1
]}

机构：

[1] Wake Forest Univ, Dept Chem, Winston Salem, NC 27109 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 547卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(97)00181-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two iron complexes, (eta(5)-Cyclopentadienyl)Fe(CO)(2)Me and (eta(5)-Methylcyclopentadienyl)Fe(CO)(2)Me, were prepared followed by their alpha, beta, and gamma cyclodextrin inclusion compounds. The included iron complexes participate in phosphine induced ligand substitution reactions under both thermal and photochemical conditions with no CO insertion/alkyl migration products observed in either case. (C) 1997 Elsevier Science S.A.

引用

页码：103 / 112

页数：10

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