Highly selective syntheses of coniferyl and sinapyl alcohols

被引：25

作者：

Lu, FC

Ralph, J

机构：

[1] USDA ARS, US Dairy Forage Res Ctr, Madison, WI 53706 USA

[2] Univ Wisconsin, Dept Forestry, Madison, WI 53706 USA

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1998年 / 46卷 / 05期

关键词：

coniferyl alcohol; sinapyl alcohol; monolignol; lignin; triacetoxyborohydride; dihydroconiferyl alcohol; coniferaldehyde; sinapaldehyde; regiospecific reduction;

D O I：

10.1021/jf970953p

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

(E)-Isomers of coniferyl and sinapyl alcohols were readily and cleanly prepared in excellent yields from commercially available coniferaldehyde and sinapaldehyde by sodium triacetoxyborohydride reduction in ethyl acetate. No 1,4-reduction products, always produced in prior methods, could be detected.

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收藏

页码：1794 / 1796

页数：3

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