Synthesis of ruthenium complexes with carbonyl and polypyridyl ligands derived from dipyrido[3,2-α:2′,3′-c]phenazine:: application to the water gas shift reaction

被引：18

作者：

Aguirre, P

López, R

Villagra, D

Azocar-Guzman, I

Pardey, AJ

Moya, SA

机构：

[1] Univ Chile, Fac Ciencias Quim & Farmaceut, Santiago, Chile

[2] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Mat, Santiago, Chile

[3] Cent Univ Venezuela, Fac Ciencias, Escuela Quim, Caracas, Venezuela

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 01期

关键词：

water gas shift reaction; ruthenium complexes; catalysts;

D O I：

10.1002/aoc.385

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The preparation and spectroscopic properties of new dipyrido[3,2-a:2',3'-c]phenazine ruthenium complexes are described. The complexes show high catalytic activity in the water gas shift reaction in a basic medium under mild conditions (P-CO = 0.9 atm at 100degreesC). Copyright (C) 2002 John Wiley Sons, Ltd.

引用

页码：36 / 41

页数：6

共 23 条

[1] Water-gas shift reaction catalyzed by mononuclear ruthenium complexes containing bipyridine and phenanthroline derivatives
Aguirre, P
Moya, SA
Sariego, R
Le Bozec, H
Pardey, AJ
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2002, 16 (10) : 597 - 600
[2] Ruthenium (II) complexes in catalytic oxidation
Aguirre, P
Sariego, R
Moya, SA
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (3-4) : 401 - 413
[3] SYNTHESIS AND STUDY OF A MIXED-LIGAND RUTHENIUM(II) COMPLEX IN ITS GROUND AND EXCITED-STATES - BIS(2,2'-BIPYRIDINE)(DIPYRIDO[3,2-A, 2',3'-C]PHENAZINE-N4N5)RUTHENIUM(II)
AMOUYAL, E
HOMSI, A
CHAMBRON, JC
SAUVAGE, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06): : 1841 - 1845
[4] [Anonymous], J AM CHEM SOC
[5] [Anonymous], POLYHEDRON
[6] Electronic effects of donor and acceptor substituents on dipyrido(3,2-a:2′,3′-c)phenazine (dppz)
Arancibia, A
Concepción, J
Daire, N
Leiva, G
Leiva, AM
Loeb, B
Del Río, R
Díaz, R
Francois, A
Saldivia, M
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (3-4) : 323 - 336
[7] COLLIN JP, 1985, NOUV J CHIM, V9, P395
[8] ELECTRONIC-STRUCTURE OF THE MOLECULAR LIGHT SWITCH [RU(BPY)2(DPPZ)]2+ (DPPZ = DIPYRIDO[3,2-A-2',3'-C]PHENAZINE) - CYCLIC VOLTAMMETRIC, UV VIS, AND EPR ENDOR STUDY OF MULTIPLY REDUCED COMPLEXES AND LIGANDS
FEES, J
KAIM, W
MOSCHEROSCH, M
MATHEIS, W
KLIMA, J
KREJCIK, M
ZALIS, S
[J]. INORGANIC CHEMISTRY, 1993, 32 (02) : 166 - 174
[9] HOMOGENEOUS CATALYSIS OF WATER GAS SHIFT REACTION BY MIXED-METAL (IRON-RUTHENIUM) CATALYSTS
FORD, PC
RINKER, RG
UNGERMANN, C
LAINE, RM
LANDIS, V
MOYA, SA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) : 4595 - 4597
[10] FORD PC, 1979, ADV CHEM SER, V173, P81

← 1 2 3 →