Heterogeneous catalysis in liquid phase transformations of importance in the industrial preparation of fine chemicals

被引:118
作者
Clark, JH [1 ]
Macquarrie, DJ [1 ]
机构
[1] Univ York, Dept Chem, York YO1 5DD, N Yorkshire, England
关键词
D O I
10.1021/op960008m
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This review focuses on the use of heterogeneous catalysts in the production of fine and speciality chemicals., The major emphasis is on those systems which have been commercialised already and those which are close to commercialisation, These include the use of TS-1 for oxidation reactions including the production of hydroquinone, caprolactam, and alkene oxides, and clay-supported catalysts such as clayzic, which are commercially available for acid-catalysed reactions, in particular Friedel-Crafts reactions, Base catalysis and acid-catalysed halogenation and nitration are also covered.
引用
收藏
页码:149 / 162
页数:14
相关论文
共 96 条
  • [61] Peregot G., 1986, STUDIES SURFACE SCI, V28, P129
  • [62] Pines H., 1981, CHEM CATALYTIC HYDRO
  • [63] SELECTIVE OXIDATION REACTIONS OVER METALLOSILICATE MOLECULAR-SIEVES - A COMPARISON OF TITANIUM AND VANADIUM SILICATES WITH MEL STRUCTURE
    RAMASWAMY, AV
    SIVASANKER, S
    RATNASAMY, P
    [J]. MICROPOROUS MATERIALS, 1994, 2 (05): : 451 - 458
  • [64] SURFACE-PROPERTIES AND POROSITIES OF SILICA AND ACID-TREATED MONTMORILLONITE CATALYST SUPPORTS - INFLUENCE ON ACTIVITIES OF SUPPORTED ZNCL2 ALKYLATION CATALYSTS
    RHODES, CN
    BROWN, DR
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (09): : 1387 - 1391
  • [65] STRUCTURAL CHARACTERIZATION AND OPTIMIZATION OF ACID-TREATED MONTMORILLONITE AND HIGH-POROSITY SILICA SUPPORTS FOR ZNCL2 ALKYLATION CATALYSTS
    RHODES, CN
    BROWN, DR
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (15): : 2269 - 2274
  • [66] ROFFIA P, 1987, Patent No. 208311
  • [67] ROFFIA P, 1990, CHIM IND-MILAN, V72, P598
  • [68] ACIDIC PROPERTIES AND CATALYTIC ACTIVITY OF NATURAL KAOLINITIC CLAYS FOR FRIEDEL-CRAFTS ALKYLATION
    SABU, KR
    SUKUMAR, R
    LALITHAMBIKA, M
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (12) : 3535 - 3541
  • [69] CYCLIC AND LINEAR OLIGOMERIZATION REACTION OF 3,4,5-TRIMETHOXYBENZYL ALCOHOL WITH A BENTONITE-CLAY
    SALMON, M
    ZAVALA, N
    MARTINEZ, M
    MIRANDA, R
    CRUZ, R
    CARDENAS, J
    GAVINO, R
    CABRERA, A
    [J]. TETRAHEDRON LETTERS, 1994, 35 (32) : 5797 - 5800
  • [70] SHELDON RA, 1973, RECL TRAV CHIM PAY B, V92, P253