Coordination, organometallic and related chemistry of tris(pyrazolyl) methane ligands

被引：238

作者：

Bigmore, HR ^{[1
]}

Lawrence, SC ^{[1
]}

Mountford, P ^{[1
]}

Tredget, CS ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

DALTON TRANSACTIONS | 2005年 / 04期

关键词：

D O I：

10.1039/b413121e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris( pyrazolyl) methanes are the neutral analogues of the widely exploited and highly useful tris( pyrazolyl) hydroborates, yet by comparison with their boron based counterparts their chemistry is underdeveloped. Recent breakthroughs in the synthesis of ring-substituted tris(pyrazolyl) methanes offer the opportunity for the development of this useful and promising class of ligand. This review summarises the current state of the coordination and organometallic chemistry of tris(pyrazolyl) methanes and highlights areas in which development is likely to occur.

引用

收藏

页码：635 / 651

页数：17

相关论文

共 160 条

[1] The substitution chemistry of the tris(3,5-dimethylpyrazolyl)-methanerhodium complex [Rh(CO)2{HC(pz′)3}]+ [J].

Adams, CJ ;

Connelly, NG ;

Emslie, DJH ;

Hayward, OD ;

Manson, T ;

Orpen, AG ;

Rieger, PH .

DALTON TRANSACTIONS, 2003, (14) :2835-2845

[2] Structures and spectra of bis-tripodal iron(II) chelates, [FeL2]2+, where L= tris(pyrazol-1-yl)methane, tris(pyridin-2-yl)methane, bis(pyrazol-1-yl)(pyridin-2-yl)methane and tris(pyridin-2-yl)-phosphine oxide.: Magnetism and spin crossover in the (pz)3CH case [J].

Anderson, PA ;

Astley, T ;

Hitchman, MA ;

Keene, FR ;

Moubaraki, B ;

Murray, KS ;

Skelton, BW ;

Tiekink, ERT ;

Toftlund, H ;

White, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (20) :3505-3512

[3] STRUCTURE, SPECTROSCOPIC AND ANGULAR-OVERLAP STUDIES OF TRIS(PYRAZOL-1-YL)METHANE COMPLEXES [J].

ASTLEY, T ;

GULBIS, JM ;

HITCHMAN, MA ;

TIEKINK, ERT .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04) :509-515

[4] Cationic osmium(II) acetyl complexes bearing pyrazolylmethane ligands: Intramolecular and interionic structure and isolation of an intermediate containing the "Os-I-Ag" moiety [J].

Bellachioma, G ;

Cardaci, G ;

Macchioni, A ;

Valentini, F ;

Zuccaccia, C ;

Foresti, E ;

Sabatino, P .

ORGANOMETALLICS, 2000, 19 (21) :4320-4326

[5] Synthesis and characterisation of ruthenium(II) arene complexes containing kappa(3)- and kappa(2)-poly(pyrazolyl)borates and methanes [J].

Bhambri, S ;

Tocher, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18) :3367-3372

[6] Synthesis, NMR studies, and molecular orbital calculations on cyclohexadienyl derivatives of (η6-arene)tris(pyrazolyl)ruthenium(II) compounds [J].

Bhambri, S ;

Bishop, A ;

Kaltsoyannis, N ;

Tocker, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (20) :3379-3390

[7] Synthesis and characterization of (arene)ruthenium(II)poly(pyrazolyl)borate and poly(pyrazolyl)methane complexes [J].

Bhambri, S ;

Tocher, DA .

POLYHEDRON, 1996, 15 (16) :2763-2770

[8] Intramolecular and interionic structural studies of novel olefin palladium(II) and platinum(II) complexes containing poly(pyrazol-1-yl)borate and -methane ligands. X-ray structures of palladium five-coordinate complexes [J].

Binotti, B ;

Bellachioma, G ;

Cardaci, G ;

Macchioni, A ;

Zuccaccia, C ;

Foresti, E ;

Sabatino, P .

ORGANOMETALLICS, 2002, 21 (02) :346-354

[9] SYNTHESIS OF PYRAZOLYL-BORATE, PYRAZOLYL-ALUMINATE, PYRAZOLYL-GALLATE AND PYRAZOYL-INDATE LIGANDS, AND THEIR CHELATING PROPERTIES TOWARDS COBALT(II), NICKEL(II), COPPER(II), AND ZINC(II) [J].

BREAKELL, KR ;

PATMORE, DJ ;

STORR, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (09) :749-754

[10] A monomeric organolithium compound containing a free pyramidal carbanion in solution and in the solid state [J].

Breher, F ;

Grunenberg, J ;

Lawrence, SC ;

Mountford, P ;

Rüegger, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (19) :2521-2524

← 1 2 3 4 5 6 7 8 9 10 →