An efficient Rh-catalyst system for the intramolecular [4+2] and [5+2] cycloaddition reactions

被引：82

作者：

Wang, B ^{[1
]}

Cao, P ^{[1
]}

Zhang, XM ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 42期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)01432-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new Rh-catalyst system has been developed for the [4+2] and [5+2] cycloaddition reactions. This new system shows high reactivity at room temperature and the Rh-center bears tunable phosphine ligands. Up to 1000 turnovers have been obtained for the [4+2] cycloaddition reaction at room temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8041 / 8044

页数：4

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