Rhodium catalyzed intramolecular [4+2] cycloisomerization reactions

被引：97

作者：

Gilbertson, SR ^{[1
]}

Hoge, GS ^{[1
]}

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 15期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(98)00265-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rhodium catalyst is reported that catalyzes the cycloisomerization of dieneynes and trienes. This cycloisomerization reaction, formally the equivalent of an unactivated Diels-Alder reaction, proceeds at room temperature with [Rh(DIPHOS)(CH2Cl2)(2)] SbF6 as the catalyst. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2075 / 2078

页数：4

共 16 条

[1] Asymmetric catalytic intramolecular hydroacylation of 4-substituted pent-4-enals to beta-substituted cyclopentanones
Barnhart, RW
McMorran, DA
Bosnich, B
[J]. CHEMICAL COMMUNICATIONS, 1997, (06) : 589 - 590
[2] BUCHHOLZ H, 1972, COORDIN CHEM REV, V8, P129
[3] OLIGOMERIZATION CATALYSTS .3. CYCLOCODIMERIZATION OF CONJUGATED DIENES WITH ACETYLENIC HYDROCARBONS CATALYZED BY IRON(O) COMPLEXES . SYNTHESIS OF 1,2-DIPHENYL-1,4-CYCLOHEXADIENE
CARBONARO, A
GRECO, A
DALLASTA, G
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (10) : 3948 - +
[4] Chiral rhodium complexes as catalysts in Diels-Alder reactions
Carmona, D
Cativiela, C
GarciaCorreas, R
Lahoz, FJ
Lamata, MP
Lopez, JA
deViu, MPLR
Oro, LA
SanJose, E
Viguri, F
[J]. CHEMICAL COMMUNICATIONS, 1996, (10) : 1247 - 1248
[5] DAVIS R, 1975, CHEM COMMUN, P405
[6] DIECK HT, 1983, ANGEW CHEM INT EDIT, V22, P778
[7] GENET JP, 1979, TETRAHEDRON LETT, P1499
[8] NOVEL CYCLIZATION REACTIONS ON TRANSITION-METAL TEMPLATES - THE CATALYSIS OF INTRAMOLECULAR [4 + 2] CYCLOADDITIONS BY LOW VALENT RHODIUM COMPLEXES
JOLLY, RS
LUEDTKE, G
SHEEHAN, D
LIVINGHOUSE, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (12) : 4965 - 4966
[9] Transition metal-mediated cycloaddition reactions
Lautens, M
Klute, W
Tam, W
[J]. CHEMICAL REVIEWS, 1996, 96 (01) : 49 - 92
[10] CYCLO-CODIMERIZATION OF 1,3-BUTADIENE DERIVATIVES WITH NONACTIVATED TERMINAL ACETYLENES CATALYZED BY CATIONIC RHODIUM(I) COMPLEX
MATSUDA, I
SHIBATA, M
SATO, S
IZUMI, Y
[J]. TETRAHEDRON LETTERS, 1987, 28 (29) : 3361 - 3362

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