Rhodium catalyzed intramolecular [4+2] cycloisomerization reactions

被引：97

作者：

Gilbertson, SR ^{[1
]}

Hoge, GS ^{[1
]}

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 15期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(98)00265-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rhodium catalyst is reported that catalyzes the cycloisomerization of dieneynes and trienes. This cycloisomerization reaction, formally the equivalent of an unactivated Diels-Alder reaction, proceeds at room temperature with [Rh(DIPHOS)(CH2Cl2)(2)] SbF6 as the catalyst. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2075 / 2078

页数：4

共 16 条

[11] ON THE ASYMMETRIC RH(I) CATALYZED [4+2] CYCLOISOMERIZATION REACTION - ELECTRONIC AND TORSIONAL LIGAND CONTROL OF ABSOLUTE STEREOSELECTION
MCKINSTRY, L
LIVINGHOUSE, T
[J]. TETRAHEDRON, 1994, 50 (21) : 6145 - 6154
[12] ALKYNES AND CUMULENES .9. PALLADIUM(O)-CATALYZED DIMERIZATION OF 1,2,4-PENTATRIENE (VINYLALLENE)
SIEGEL, H
GERMER, A
BINGER, P
HOPF, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (09): : 3112 - 3118
[13] MONOOLEFIN AND DIENE CYCLOADDITION INDUCED BY TRANSITION-METAL CARBONYLS - CYCLO-DIMERIZATION OF 5,6-DIMETHYLIDENE-7-OXABICYCLO[2.2.1]HEPT-2-ENE CATALYZED BY DODECACARBONYLTRIOSMIUM
VIOGET, P
BONIVENTO, M
ROULET, R
VOGEL, P
[J]. HELVETICA CHIMICA ACTA, 1984, 67 (06) : 1638 - 1646
[14] TRANSITION-METAL-CATALYZED [5+2] CYCLOADDITIONS OF VINYLCYCLOPROPANES AND ALKYNES - A HOMOLOG OF THE DIELS-ALDER REACTION FOR THE SYNTHESIS OF 7-MEMBERED RINGS
WENDER, PA
TAKAHASHI, H
WITULSKI, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (16) : 4720 - 4721
[15] NICKEL-CATALYZED INTRAMOLECULAR [4 + 4] CYCLOADDITIONS - A NEW METHOD FOR THE SYNTHESIS OF POLYCYCLES CONTAINING 8-MEMBERED RINGS
WENDER, PA
IHLE, NC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (15) : 4678 - 4679
[16] NICKEL-CATALYZED INTRAMOLECULAR [4 + 2] DIENYNE CYCLO-ADDITIONS - AN EFFICIENT NEW METHOD FOR THE SYNTHESIS OF POLYCYCLES CONTAINING CYCLOHEXA-1,4-DIENES
WENDER, PA
JENKINS, TE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) : 6432 - 6434

← 1 2 →