[60]fullerene diol issued from pentaerythritol derivatives

被引：8

作者：

Chopin, S ^{[1
]}

Delaunay, J ^{[1
]}

Cousseau, J ^{[1
]}

机构：

[1] Univ Angers, CNRS, Lab Chim Ingn Mol & Mat Angers, UMR 6200, F-49045 Angers 01, France

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 03期

关键词：

C-60(2-); pentaerythritol; C-60; chemistry; diol;

D O I：

10.1016/j.tetlet.2004.11.132

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new [60]fullerene diol is synthesized in good yield, in two steps starting front reaction of C-60(2-) anion with the benzyl-ideneacetal derived from 2,2-bis(iodomethyl)-1,3-propanediol. The corresponding [60]fullerene bis-mesylate is also formed in a similar way starting from bis-iodo bis-mesylate compound in the same series. The scope of this fullerene diol in synthesis is exemplified by its easy esterification with 4-formyl benzoyl chloride. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：373 / 376

页数：4

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