Generation and intramolecular reactivity of acyl radicals from alkynylthiol esters under reducing tin-free conditions

被引：78

作者：

Benati, L

Calestani, G

Leardini, R

Minozzi, M

Nanni, D

Spagnolo, P

Strazzari, S

机构：

[1] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy

[2] Univ Parma, Dipartimento Chim Gen & Inorgan Analit & Chim Fis, I-43100 Parma, Italy

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 08期

关键词：

D O I：

10.1021/ol034252r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The radical chain reaction of benzenethiol with alkynylthiol esters provides a new, valuable protocol for the tin-free generation of acyl radicals that arise from intramolecular substitution at sulfur by the initial sulfanylvinyl radicals.

引用

页码：1313 / 1316

页数：4

共 23 条

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