Synthesis and electrochemical properties of tetrathiafulvalene derived amino acids and peptides

被引：20

作者：

Booth, S ^{[1
]}

Wallace, ENK ^{[1
]}

Singhal, K ^{[1
]}

Bartlett, PN ^{[1
]}

Kilburn, JD ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 09期

关键词：

D O I：

10.1039/a800759d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthetic route to a tetrathiafulvalene (TTF) derived aspartic acid derivative 18, with suitable orthogonal protecting groups has been developed. The aspartic acid derivative 18 can be used in the synthesis of peptides, as exemplified by the synthesis of di-, tri- and tetra-peptides 21-23. Preliminary electrochemical studies of these novel peptides indicate that they may well undergo conformational reorganisation upon oxidation of the TTF moieties.

引用

页码：1467 / 1474

页数：8

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