Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a bridge with unusual 4,5-diazospirobifluorene and perchlorate

被引：58

作者：

Wang, CC ^{[1
]}

Yang, CH

Tseng, SM

Lin, SY

Wu, TY

Fuh, MR

Lee, GH

Wong, KT

Chen, RT

Cheng, YM

Chou, PT

机构：

[1] Soochow Univ, Dept Chem, Taipei 111, Taiwan

[2] Natl Taiwan Univ, Instrumentat Ctr, Taipei 106, Taiwan

[3] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 16期

关键词：

D O I：

10.1021/ic0351794

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polymeric silver complex, [Ag-2(L-2)(ClO4)(2)] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag-2(L-2)](2+) dimer bridged with ClO4-. The Ag...Ag distances are 2.776(1) and 4.575(1) Angstrom incorporated by two L ligands and by a ClO4- bridge, respectively.

引用

页码：4781 / 4783

页数：3

共 26 条

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