Growth and optical properties of single-crystal tubular ZnO whiskers

被引:297
作者
Hu, JQ
Bando, Y
机构
[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, Nanomat Lab, Tsukuba, Ibaraki 3050044, Japan
关键词
D O I
10.1063/1.1558899
中图分类号
O59 [应用物理学];
学科分类号
摘要
The growth of single-crystal tubular ZnO whiskers was achieved via a process of first reduction and following oxidation of ZnS powders. The products were characterized using x-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, and photoluminescence spectroscopy. The whiskers are tubular single crystals with the [001] growth crystallographic direction, and most have outer diameters of similar to400 nm, lengths of up to 15 mum, and wall thickness range of 100-150 nm. Room-temperature photoluminescence spectrum of the whiskers reveals a strong and sharp UV emission band at 381 nm and a weak and broad green emission band at 583 nm. Possible growth mechanism of the ZnO whiskers was briefly discussed. (C) 2003 American Institute of Physics.
引用
收藏
页码:1401 / 1403
页数:3
相关论文
共 23 条
[11]   Complex nature of the UV and visible fluorescence of Colloidal ZnO nanoparticles [J].
Monticone, S ;
Tufeu, R ;
Kanaev, AV .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (16) :2854-2862
[12]   A laser ablation method for the synthesis of crystalline semiconductor nanowires [J].
Morales, AM ;
Lieber, CM .
SCIENCE, 1998, 279 (5348) :208-211
[13]   Low-cost synthesis of vanadium oxide nanotubes via two novel non-alkoxide routes [J].
Niederberger, M ;
Muhr, HJ ;
Krumeich, F ;
Bieri, F ;
Günther, D ;
Nesper, R .
CHEMISTRY OF MATERIALS, 2000, 12 (07) :1995-2000
[14]   Epitaxial growth of zinc oxide whiskers by chemical-vapor deposition under atmospheric pressure [J].
Satoh, M ;
Tanaka, N ;
Ueda, Y ;
Ohshio, S ;
Saitoh, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1999, 38 (5B) :L586-L589
[15]   On the optical band gap of zinc oxide [J].
Srikant, V ;
Clarke, DR .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (10) :5447-5451
[16]   Mechanisms behind green photoluminescence in ZnO phosphor powders [J].
Vanheusden, K ;
Warren, WL ;
Seager, CH ;
Tallant, DR ;
Voigt, JA ;
Gnade, BE .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (10) :7983-7990
[17]   VAPOR-LIQUID-SOLID MECHANISM OF SINGLE CRYSTAL GROWTH ( NEW METHOD GROWTH CATALYSIS FROM IMPURITY WHISKER EPITAXIAL + LARGE CRYSTALS SI E ) [J].
WAGNER, RS ;
ELLIS, WC .
APPLIED PHYSICS LETTERS, 1964, 4 (05) :89-&
[18]   ZnO quantum particle thin films fabricated by electrophoretic deposition [J].
Wong, EM ;
Searson, PC .
APPLIED PHYSICS LETTERS, 1999, 74 (20) :2939-2941
[19]   Heterostructures of ZnO-Zn coaxial nanocables and ZnO nanotubes [J].
Wu, JJ ;
Liu, SC ;
Wu, CT ;
Chen, KH ;
Chen, LC .
APPLIED PHYSICS LETTERS, 2002, 81 (07) :1312-1314
[20]   Nonlinear optical transmission in VOx nanotubes and VOx nanotube composites [J].
Xu, JF ;
Czerw, R ;
Webster, S ;
Carroll, DL ;
Ballato, J ;
Nesper, R .
APPLIED PHYSICS LETTERS, 2002, 81 (09) :1711-1713