High yield olefination of a wide scope of aryl chlorides catalyzed by the phosphinito palladium PCP pincer complex:: [PdCl{C6H3(OPPri2)2-2,6}]

被引：296

作者：

Morales-Morales, D ^{[1
]}

Redón, R ^{[1
]}

Yung, C ^{[1
]}

Jensen, CM ^{[1
]}

机构：

[1] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b004412l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[PdCl{C6H3(OPPr2i)(2)-2,6}] efficiently catalyzes the olefination of a broad scope of aryl chlorides; as a result of the high thermal stability of the catalyst, the coupled products are obtained in excellent and in many cases nearly quantitative yields.

引用

收藏

页码：1619 / 1620

页数：2

相关论文

共 29 条

[1]

Beller M, 1998, SYNLETT, P792

[2]

Ben-David Y., 1995, ORGANOMETALLICS, V11

[3]

Brase S., 1998, METAL CATALYZED CROS

[4] RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION [J].

CABRI, W ;

CANDIANI, I .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :2-7

[5] Thermodynamics and mechanism of the reversible tin-to-palladium transmetalation of the furyl group [J].

Cotter, WD ;

Barbour, L ;

McNamara, KL ;

Hechter, R ;

Lachicotte, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) :11016-11017

[6] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].

DE MEIJERE, A ;

MEYER, FE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411

[7] Catalytic dehydrogenation of cycloalkanes to arenes by a dihydrido iridium P-C-P pincer complex [J].

Gupta, M ;

Hagen, C ;

Kaska, WC ;

Cramer, RE ;

Jensen, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (04) :840-841

[8] A highly active alkane dehydrogenation catalyst: Stabilization of dihydrido rhodium and iridium complexes by a P-C-P pincer-ligand [J].

Gupta, M ;

Hagen, C ;

Flesher, RJ ;

Kaska, WC ;

Jensen, CM .

CHEMICAL COMMUNICATIONS, 1996, (17) :2083-2084

[9]

GUPTA M, 1997, CHEM COMMUN, P2083

[10]

Heck R.F., 1991, Comprehensive Organic Synthesis, V4, P833, DOI DOI 10.1016/B978-0-08-052349-1.00110-4