Reactions of a chelated cyclopentadienylcobalt(I) complex with 3,3-disubstituted cyclopropenes: Formation of isoprene, vinylcarbene, and 1-phosphadiene ligands at the metal

被引：50

作者：

Foerstner, J

Kakoschke, A

Stellfeldt, D

Butenschon, H

Wartchow, R

机构：

[1] Leibniz Univ Hannover, Inst Organ Chem, D-30167 Hannover, Germany

[2] Leibniz Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 05期

关键词：

D O I：

10.1021/om970851o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Di-tert-butylphosphanyl-P-ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 were treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert-butylphosphaethyne to give unusual coupling products.

引用

页码：893 / 896

页数：4

共 33 条

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