High-resolution NMR of quadrupolar nuclei in solids: the satellite-transition magic angle spinning (STMAS) experiment

被引：116

作者：

Ashbrook, SE

Wimperis, S

机构：

[1] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

[2] Univ Cambridge, Dept Earth Sci, Cambridge CB2 3EQ, England

来源：

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 2004年 / 45卷 / 1-2期

关键词：

NMR; STMAS; MQMAS; satellite transition; multiple quantum; quadrupolar nuclei; magic angle spinning;

D O I：

10.1016/j.pnmrs.2004.04.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The acquisition of high-resolution NMR spectra of half-integer quadrupolar nuclei in solids through the satellite-transition magnetic angle spinning (ST-MAS) experiment, was investigated. For crsystalline material smples, two-dimensional STMAS NMR spectra consist ridge-like lineshapes. The short range by these materials were analyzed by NMR. It was found that the STMAS is a major NMR method that has good sensitivity and can reveal information about structure and dynamics.

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收藏

页码：53 / 108

页数：56

相关论文

共 102 条

[41]

FREEMAN R, 1997, HDB NUCL MAGNETIC RE, P88

[42] ISOTROPIC SPECTRA OF HALF-INTEGER QUADRUPOLAR SPINS FROM BIDIMENSIONAL MAGIC-ANGLE-SPINNING NMR [J].

FRYDMAN, L ;

HARWOOD, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5367-5368

[43] Isotropic NMR spectra of half-integer quadrupolar nuclei using satellite transitions and magic-angle spinning [J].

Gan, ZH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (13) :3242-3243

[44] Third-order effect in solid-state NMR of quadrupolar nuclei [J].

Gan, ZH ;

Srinivasan, P ;

Quine, JR ;

Steuernagel, S ;

Knott, B .

CHEMICAL PHYSICS LETTERS, 2003, 367 (1-2) :163-169

[45] Satellite transition magic-angle spinning nuclear magnetic resonance spectroscopy of half-integer quadrupolar nuclei [J].

Gan, ZH .

JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (24) :10845-10853

[46] VARIABLE-ANGLE SAMPLE-SPINNING HIGH-RESOLUTION NMR OF SOLIDS [J].

GANAPATHY, S ;

SCHRAMM, S ;

OLDFIELD, E .

JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (09) :4360-4365

[47] PURE-ABSORPTION-MODE LINESHAPES AND SENSITIVITY IN 2-DIMENSIONAL DYNAMIC-ANGLE SPINNING NMR [J].

GRANDINETTI, PJ ;

BALTISBERGER, JH ;

LLOR, A ;

LEE, YK ;

WERNER, U ;

EASTMAN, MA ;

PINES, A .

JOURNAL OF MAGNETIC RESONANCE SERIES A, 1993, 103 (01) :72-81

[48] QUADRUPOLAR EFFECTS TRANSFERRED TO SPIN-1/2 MAGIC-ANGLE SPINNING SPECTRA OF SOLIDS [J].

HARRIS, RK ;

OLIVIERI, AC .

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1992, 24 :435-456

[49] NMR nomenclature: Nuclear spin properties and conventions for chemical shifts - IUPAC recommendations 2001 (Reprinted from Pure Appl. Chem, vol 73, pg 1795-1818, 2001) [J].

Harris, RK ;

Becker, ED ;

de Menezes, SMC ;

Goodfellow, R ;

Granger, P .

SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2002, 22 (04) :458-483

[50]

HORE PJ, 2000, NMR TOOLKIT, pCH6

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