Liquid phase bromination of phenols using potassium bromide and hydrogen peroxide over zeolites

被引:63
作者
Narender, N
Mohan, KVVK
Reddy, RV
Srinivasu, P
Kulkarni, SJ [1 ]
Raghavan, KV
机构
[1] Indian Inst Chem Technol, Catalysis Grp, Hyderabad 500007, Andhra Pradesh, India
[2] Indian Inst Chem Technol, Catalysis & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India
关键词
zeolites; oxybromination; potassium bromide; hydrogen peroxide; para-selectivity;
D O I
10.1016/S1381-1169(02)00131-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An efficient, simple, mild and regioselective method for oxybromination of phenols catalyzed by CrZSM-5(30) is reported. The electrophilic substitution of bromine generated in situ from KBr as a bromine source and hydrogen peroxide as an oxidant. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:73 / 77
页数:5
相关论文
共 21 条
[1]   N-BROMOSUCCINIMIDE DIBROMODIMETHYLHYDANTOIN IN AQUEOUS BASE - A PRACTICAL METHOD FOR THE BROMINATION OF ACTIVATED BENZOIC-ACIDS [J].
AUERBACH, J ;
WEISSMAN, SA ;
BLACKLOCK, TJ ;
ANGELES, MR ;
HOOGSTEEN, K .
TETRAHEDRON LETTERS, 1993, 34 (06) :931-934
[2]   Simple and efficient chlorination and bromination of aromatic compounds with aqueous TBHP (or H2O2) and a hydrohalic acid. [J].
Barhate, NB ;
Gajare, AS ;
Wakharkar, RD ;
Bedekar, AV .
TETRAHEDRON LETTERS, 1998, 39 (35) :6349-6350
[3]  
BOVONSOMBAT P, 1993, SYNTHESIS-STUTTGART, P237
[4]  
Clark J. H., 1995, CHEM WASTE MINIMIZAT
[5]   QUATERNARY AMMONIUM-SALTS AS BIFUNCTIONAL CATALYSTS IN THE OXYBROMINATION OF AROMATIC-COMPOUNDS BY AQUEOUS HYDROGEN BROMIDE HYDROGEN-PEROXIDE [J].
DAKKA, J ;
SASSON, Y .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (19) :1421-1422
[6]   ELECTROPHILIC HALOGENATION OF AROMATICS AND HETEROAROMATICS WITH N-HALOSUCCINIMIDES IN A SOLID-LIQUID SYSTEM USING AN H+ ION-EXCHANGER OR ULTRASONIC IRRADIATION [J].
GOLDBERG, Y ;
ALPER, H .
JOURNAL OF MOLECULAR CATALYSIS, 1994, 88 (03) :377-383
[7]  
HOLDERICH WF, 1991, STUD SURF SCI CATAL, V58, P631
[8]   A MILD SELECTIVE MONOBROMINATION REAGENT SYSTEM FOR ALKOXYBENZENES - N-BROMOSUCCINIMIDE-SILICA GEL [J].
KONISHI, H ;
ARITOMI, K ;
OKANO, T ;
KIJI, J .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (02) :591-593
[9]  
Laszlo P, 1987, Preparative Chemistry using Supported Reagents
[10]   QUINONES .7. HALOGENATION AND OXIDATIVE HALOGENATION OF PHENOLS WITH HYDROGEN HALIDES AND HYDROGEN PEROXIDE - SYNTHESIS OF PARA-CHLORANIL AND PARA-BROMANIL [J].
LUBBECKE, H ;
BOLDT, P .
TETRAHEDRON, 1978, 34 (10) :1577-1579