Chemoselective reaction system using a two inlet micro-flow reactor: application to carbonyl allylation

被引：40

作者：

Amemiya, Fumihiro ^{[1
]}

Fuse, Keishi ^{[1
]}

Fuchigami, Toshio ^{[1
]}

Atobe, Mahito ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Yokohama, Kanagawa 2668502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 16期

关键词：

PARALLEL LAMINAR-FLOW; ELECTROCATALYTIC ACTIVITY; REDUCTION; ELECTROREDUCTION; HYDROGENATION; ALDEHYDES; REAGENTS; ALCOHOLS; KINETICS; HALIDES;

D O I：

10.1039/b926943f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new strategy for chemoselective reaction using a two inlet micro-flow reactor is described. In this system, the combined use of suitable flow mode and corresponding cathode material enables chemoselective cathodic reduction to control the product regioselectivity in carbonyl allylation.

引用

页码：2730 / 2732

页数：3

共 40 条

[31] Tamaru Y., 1999, Perspectives in Organopalladium Chemistry for the XXI Century, P215
[32] The Domino Multicomponent Allylation Reaction for the Stereoselective Synthesis of Homoallylic Alcohols
Tietze, Lutz F.
Kinzel, Tom
Brazel, C. Christian
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (02) : 367 - 378
[33] REGIOSELECTIVITY IN ELECTROCHEMICAL ALLYLATION OF CARBONYL-COMPOUNDS - A SYNTHESIS OF EGOMAKETONE BY REGIOSELECTIVE ALLYLATION
TOKUDA, M
SATOH, S
SUGINOME, H
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (23) : 5608 - 5613
[34] Regio- and chemoselective enzymatic N-oxygenation in vivo, in vitro, and in flow
Winkler, Robert
Richter, Martin E. A.
Knuepfer, Uwe
Merten, Dirk
Hertweck, Christian
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (47) : 8016 - 8018
[35] SELECTIVE REACTIONS USING ALLYLIC METALS
YAMAMOTO, Y
ASAO, N
[J]. CHEMICAL REVIEWS, 1993, 93 (06) : 2207 - 2293
[36] YOSHIDA J, 2007, ELECTROCHEMISTRY, V75, P58
[37] Flash chemistry: Fast chemical synthesis by using microreactors
Yoshida, Jun-ichi
Nagaki, Aiichiro
Yamada, Takeshi
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (25) : 7450 - 7459
[38] Young IS, 2009, NAT CHEM, V1, P193, DOI [10.1038/NCHEM.216, 10.1038/nchem.216]
[39] Enantioselective catalytic allylation of carbonyl groups by Umpolung of π-allyl palladium complexes
Zanoni, G
Gladiali, S
Marchetti, A
Piccinini, P
Tredici, I
Vidari, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (07) : 846 - 849
[40] Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals
Zhou, Chun-Hui
Beltramini, Jorge N.
Fan, Yong-Xian
Lu, G. Q.
[J]. CHEMICAL SOCIETY REVIEWS, 2008, 37 (03) : 527 - 549

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