Materials for Solid Oxide Fuel Cells

被引:1153
作者
Jacobson, Allan J. [1 ]
机构
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
关键词
OXYGEN-ION CONDUCTION; CERIA-BASED ELECTROLYTES; LA(SR)FEO3 SOFC CATHODE; MAGNESIUM-DOPED LAGAO3; ELECTRICAL-PROPERTIES; PEROVSKITE-TYPE; ELECTROCHEMICAL PROPERTIES; CRYSTAL-STRUCTURE; ANODE MATERIALS; DIRECT OXIDATION;
D O I
10.1021/cm902640j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solid oxide fuel cells (SOFCs) have the promise to improve energy efficiency and to provide society with a clean energy producing technology. The high temperature of operation (500-1000 degrees C) enables the solid oxide fuel cell to operate with existing fossil fuels and to be efficiently coupled with turbines to give very high efficiency conversion of fuels to electricity. Solid oxide fuel cells are complex electrochemical devices that contain three basic components, a porous anode, an electrolyte membrane, and a porous cathode. In this short review, a survey of the types and properties of materials that have been considered for each of these components is presented with an emphasis on the requirements for operation at intermediate temperature (500-800 degrees C). Some directions for future research are discussed.
引用
收藏
页码:660 / 674
页数:15
相关论文
共 191 条
[71]   Lanthanum- and Oxygen-Deficient Crystal Structures of Oxide-Ion Conducting Apatite-Type Silicates [J].
Iwata, Tomoyuki ;
Bechade, Emilie ;
Fukuda, Koichiro ;
Masson, Olivier ;
Julien, Isabelle ;
Champion, Eric ;
Thomas, Philippe .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (11) :3714-3720
[72]   Electrochemical performance of La-doped Sr2MgMoO6-δ in natural gas [J].
Ji, Yuan ;
Huang, Yun-Hui ;
Ying, Jie-Rong ;
Goodenough, John B. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (08) :1881-1885
[73]   Development of lanthanum strontium manganite perovskite cathode materials of solid oxide fuel cells: a review [J].
Jiang, San Ping .
JOURNAL OF MATERIALS SCIENCE, 2008, 43 (21) :6799-6833
[74]   (La0.75Sr0.25)(Cr0.5Mn0.5)O3/YSZ composite anodes for methane oxidation reaction in solid oxide fuel cells [J].
Jiang, SP ;
Chen, XJ ;
Chan, SH ;
Kwok, JT ;
Khor, KA .
SOLID STATE IONICS, 2006, 177 (1-2) :149-157
[75]   Local defect structures and ion transport mechanisms in the oxygen-excess apatite La9.67(SiO4)6O2.5 [J].
Jones, Alison ;
Slater, Peter R. ;
Islam, M. Saiful .
CHEMISTRY OF MATERIALS, 2008, 20 (15) :5055-5060
[76]   Atomic-scale insight into LaFeO3 perovskite:: Defect nanoclusters and ion migration [J].
Jones, Alison ;
Islam, M. Saiful .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (12) :4455-4462
[77]   Microstructure of cobalt oxide doped sintered ceria solid solutions [J].
Jud, E ;
Zhang, Z ;
Sigle, W ;
Gauckler, LJ .
JOURNAL OF ELECTROCERAMICS, 2006, 16 (03) :191-197
[78]   Solid oxide fuel cell using (Ba0.3Sr0.2La0.5)InO2.75 electrolyte [J].
Kakinuma, K ;
Arisaka, T ;
Yamamura, H ;
Atake, T .
SOLID STATE IONICS, 2004, 175 (1-4) :139-143
[79]   Oxide-ion conductivity of the perovskite-type solid-solution system, (Ba1-x-ySrxLay)2In2O5+y [J].
Kakinuma, K ;
Yamamura, H ;
Haneda, H ;
Atake, T .
SOLID STATE IONICS, 2002, 154 :571-576
[80]   ORIGIN OF FILAMENTOUS CARBON FORMATION FROM REACTION OF PROPANE OVER NICKEL [J].
KEEP, CW ;
BAKER, RTK ;
FRANCE, JA .
JOURNAL OF CATALYSIS, 1977, 47 (02) :232-238