The phenol ortho-oxygenation by mononuclear copper( I) complexes requires a dinuclear μ-η2 : η2-peroxodicopper(II) complex rather than mononuclear CuO2 species

被引：49

作者：

Battaini, G

De Carolis, M

Monzani, E

Tuczek, F

Casella, L

机构：

[1] Univ Pavia, Dipartimento Chim Gen, I-27100 Pavia, Italy

[2] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 06期

关键词：

D O I：

10.1039/b212683d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mononuclear complex [Cu(L)](+) performs the ortho-oxygenation of an exogeneous phenol through the formation of a dinuclear mu-eta(2):eta(2)-peroxodicopper(II) intermediate, which is so far the only type of copper-dioxygen complex that mediates the tyrosinase monophenolase reaction.

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页码：726 / 727

页数：2

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