Electrogenerated chemiluminescence of CdS spherical assemblies

被引：103

作者：

Ren, T

Xu, JZ

Tu, YF

Xu, S

Zhu, JJ ^{[1
]}

机构：

[1] Nanjing Univ, Dept Chem, Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China

[2] Suzhou Univ, Dept Chem, Suzhou 215006, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2005年 / 7卷 / 01期

基金：

中国国家自然科学基金;

关键词：

electrochemistry; electrogenerated chemiluminescence; CdS spherical assemblies;

D O I：

10.1016/j.elecom.2004.10.005

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We report the first observation of electrogenerated chemiluminescence (ECL) from US spherical assemblies in both nonaqueous system and aqueous system. The US spherical assemblies consist of US nanocrystals about 5 nm in diameter. Four ECL peaks were found under cyclic voltammetric conditions. According to the annihilation mechanism and two-equivalent adsorbed surface state theory, the mechanism for ECL peaks was proposed. The morphology of the US spherical assemblies is proved to play an important role in maintaining the stability of partial electrogenerated species to generate the ECL light. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：5 / 9

页数：5

共 12 条

[1] Semiconductor clusters, nanocrystals, and quantum dots [J].