Ni(III) vs. Ni(II)-thiyl radical:: charge-delocalisation in a binuclear Ni(III)Ni(II)-dithiolate complex

被引：31

作者：

Branscombe, NDJ

Atkins, AJ

Marin-Becerra, A

McInnes, EJL

Mabbs, FE

McMaster, J

Schröder, M

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Manchester, Dept Chem, EPSRC EPR Serv Ctr, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 09期

关键词：

D O I：

10.1039/b300245d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Multi-frequency EPR spectroscopy on Ni-61-labelled samples of [Ni-2(L)](3+) confirms extensive charge-delocalisation between the Ni(III) centre and thiolate donors in the Ni(II) Ni(III) complex.

引用

页码：1098 / 1099

页数：2

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