Oxidation of aliphatic amines by aqueous chlorine

被引：112

作者：

Abia, L ^{[1
]}

Armesto, XL ^{[1
]}

Canle, M ^{[1
]}

García, MV ^{[1
]}

Santaballa, JA ^{[1
]}

机构：

[1] Univ A Coruna, Fac Ciencias, Dept Quim Fundamental & Ind, E-15071 La Coruna, Galicia, Spain

来源：

TETRAHEDRON | 1998年 / 54卷 / 3-4期

关键词：

D O I：

10.1016/S0040-4020(97)10312-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of aliphatic amines by aqueous chlorine has been studied. The kinetic behaviour is similar for primary, secondary and tertiary aliphatic amines, the elementary step being the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the free amino group. Chlorination of aliphatic primary and secondary amines involves some water molecules in the transition state. Inductive effects are also discussed. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：521 / 530

页数：10

共 34 条

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