Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons

被引：1332

作者：

Roy, Somnath C.

Varghese, Oomman K.

Paulose, Maggie

Grimes, Craig A. ^{[1
]}

机构：

[1] Penn State Univ, Dept Elect Engn, University Pk, PA 16802 USA

来源：

ACS NANO | 2010年 / 4卷 / 03期

基金：

美国国家科学基金会;

关键词：

carbon dioxide recycling; global warming; photocatalytic conversion; TiO2 nanotube array; electrochemical anodization; hydrocarbon fuels; gas chromatography; TIO2 NANOTUBE ARRAYS; DOPED TITANIUM-DIOXIDE; HIGH-CURRENT DENSITY; ELECTROCHEMICAL REDUCTION; CO2; REDUCTION; ROOM-TEMPERATURE; ELECTROCATALYTIC REDUCTION; GREENHOUSE-GAS; AMBIENT-TEMPERATURE; COPPER ELECTRODE;

D O I：

10.1021/nn9015423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The past several decades have seen a significant rise in atmospheric carbon dioxide levels resulting from the combustion of hydrocarbon fuels. A solar energy based technology to recycle carbon dioxide into readily transportable hydrocarbon fuel (i.e., a solar fuel) would help reduce atmospheric CO2 levels and partly fulfill energy demands within the present hydrocarbon based fuel infrastructure. We review the present status of carbon dioxide conversion techniques, with particular attention to a recently developed photocatalytic process to convert carbon dioxide and water vapor into hydrocarbon fuels using sunlight.

引用

页码：1259 / 1278

页数：20

共 157 条

[51] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE UNDER HIGH-PRESSURE ON VARIOUS ELECTRODES IN AN AQUEOUS-ELECTROLYTE
HARA, K
KUDO, A
SAKATA, T
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 391 (1-2): : 141 - 147
[52] Large current density CO2 reduction under high pressure using gas diffusion electrodes
Hara, K
Sakata, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (03) : 571 - 576
[53] Advanced materials for global carbon dioxide recycling
Hashimoto, K
Habazaki, H
Yamasaki, M
Meguro, S
Sasaki, T
Katagiri, H
Matsui, T
Fujimura, K
Izumiya, K
Kumagai, N
Akiyama, E
[J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2001, 304 (304-306): : 88 - 96
[54] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE MEDIATED BY RE(BIPY)(CO)3CL(BIPY=2,2'-BIPYRIDINE)
HAWECKER, J
LEHN, JM
ZIESSEL, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (06) : 328 - 330
[55] Photochemical charge transfer and trapping at the interface between an organic adlayer and an oxide semiconductor
Henderson, MA
White, JM
Uetsuka, H
Onishi, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (49) : 14974 - 14975
[56] PRODUCTION OF METHANE AND ETHYLENE IN ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE AT COPPER ELECTRODE IN AQUEOUS HYDROGENCARBONATE SOLUTION
HORI, Y
KIKUCHI, K
MURATA, A
SUZUKI, S
[J]. CHEMISTRY LETTERS, 1986, (06) : 897 - 898
[57] FORMATION OF HYDROCARBONS IN THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE AT A COPPER ELECTRODE IN AQUEOUS-SOLUTION
HORI, Y
MURATA, A
TAKAHASHI, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 : 2309 - 2326
[58] Deactivation of copper electrode in electrochemical reduction of CO2
Hori, Y
Konishi, H
Futamura, T
Murata, A
Koga, O
Sakurai, H
Oguma, K
[J]. ELECTROCHIMICA ACTA, 2005, 50 (27) : 5354 - 5369
[59] PRODUCTION OF CO AND CH4 IN ELECTROCHEMICAL REDUCTION OF CO2 AT METAL-ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION
HORI, Y
KIKUCHI, K
SUZUKI, S
[J]. CHEMISTRY LETTERS, 1985, (11) : 1695 - 1698
[60] ENHANCED FORMATION OF ETHYLENE AND ALCOHOLS AT AMBIENT-TEMPERATURE AND PRESSURE IN ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE AT A COPPER ELECTRODE
HORI, Y
MURATA, A
TAKAHASHI, R
SUZUKI, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (01) : 17 - 19

← 1 2 3 4 5 6 7 8 9 10 →