On chemical reactors that can count

被引:96
作者
Gorecki, J [1 ]
Yoshikawa, K
Igarashi, Y
机构
[1] Kyoto Univ, Grad Sch Sci, Dept Phys, Kyoto, Japan
[2] CREST, Kyoto, Japan
[3] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
D O I
10.1021/jp021041f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is known that spatially distributed excitable systems can transmit and process information if one relates the logical "true" state with a high concentration of a selected reagent and the logical "false" state with a low concentration of the same reagent. The information coded in the propagating pulses of concentration can be processed in properly arranged reactors. In this paper, we show how to build a reactor counting the number of pulses that arrive at a given point of space or that propagate within a signal channel. We discuss two types of such reactors. The first consists of many memory cells, and each of the arriving pulses excites a subsequent cell. The second gives the number of arriving pulses in the binary positional representation. All basic elements of these chemical counters have been tested experimentally using a photosensitive Ru-catalyzed Belousov-Zhabotinsky reaction.
引用
收藏
页码:1664 / 1669
页数:6
相关论文
共 32 条
[1]   Propagation of chemical waves at the boundary of excitable and inhibitory fields [J].
Agladze, K ;
Tóth, A ;
Ichino, T ;
Yoshikawa, K .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (29) :6677-6680
[2]   Chemical diode [J].
Agladze, K ;
Aliev, RR ;
Yamaguchi, T ;
Yoshikawa, K .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (33) :13895-13897
[3]   SPIRAL WAVES IN THE HOMOGENEOUS AND INHOMOGENEOUS BELOUSOV-ZHABOTINSKY REACTION [J].
ALIEV, RR ;
ROVINSKY, AB .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (02) :732-736
[4]   COMPUTATIONAL FUNCTIONS IN BIOCHEMICAL REACTION NETWORKS [J].
ARKIN, A ;
ROSS, J .
BIOPHYSICAL JOURNAL, 1994, 67 (02) :560-578
[5]   OSCILLATIONS IN CHEMICAL SYSTEMS .2. THOROUGH ANALYSIS OF TEMPORAL OSCILLATION IN BROMATE-CERIUM-MALONIC ACID SYSTEM [J].
FIELD, RJ ;
NOYES, RM ;
KOROS, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (25) :8649-&
[6]   STOCHASTIC EFFECTS IN PROPAGATION OF IMPULSES - THE BELOUSOV-ZHABOTINSKII REACTION [J].
FRANKOWICZ, M ;
KAWCZYNSKI, AL ;
GORECKI, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (03) :1265-1268
[7]  
Hammett L. P., 1940, Physical organic chemistry
[8]  
reaction rates, equilibria, and mechanisms
[9]   PATTERN-RECOGNITION IN COUPLED CHEMICAL KINETIC SYSTEMS [J].
HJELMFELT, A ;
SCHNEIDER, FW ;
ROSS, J .
SCIENCE, 1993, 260 (5106) :335-337
[10]   Noise-supported travelling waves in sub-excitable media [J].
Kádár, S ;
Wang, JC ;
Showalter, K .
NATURE, 1998, 391 (6669) :770-772