Synthesis of bulky phosphines by rhodium-catalyzed formal [2+2+2] cycloaddition reactions of tethered diynes with 1-alkynylphosphine sulfides

被引：60

作者：

Kondoh, Azusa ^{[1
]}

Yorimitsu, Hideki ^{[1
]}

Oshima, Koichiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 22期

关键词：

D O I：

10.1021/ja071622o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of tethered diynes with 1-alkynylphosphine sulfides under rhodium catalysis provides the corresponding phosphine sulfides having a bulky aryl group. The following desulfidation yields bulky phosphines that will potentially serve as ligands in transition-metal-catalyzed reactions.

引用

页码：6996 / +

页数：3

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