Direct catalytic oxyamination of benzene to aniline over Cu(II) nanoclusters supported on CuCr2O4 spinet nanoparticles via simultaneous activation of C-H and N-H bonds

被引：30

作者：

Acharyya, Shankha S. ^{[1
]}

Ghosh, Shilpi ^{[1
]}

Bal, Rajaram ^{[1
]}

机构：

[1] Indian Inst Petr, CSIR, Catalyt Convers & Proc Div, Dehra Dun 248005, Uttar Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 87期

关键词：

COPPER CHROMITE CATALYST; OXIDATIVE AMINATION; SELECTIVE OXIDATION; CATALOREACTANT; NIO/ZRO2; AMMONIA; TOLUENE;

D O I：

10.1039/c4cc02937b

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

We report the facile synthesis of a highly efficient, reusable catalyst comprising Cu(II) nanoclusters supported on CuCr2O4 spinet nanoparticles for the oxyamination of benzene to aniline (H2O2 + NH3) under mild aqueous reaction conditions. The synergy between the Cu(II) nanoclusters and CuCr2O4 spinet nanoparticles plays the most vital role towards its high catalytic activity.

引用

页码：13311 / 13314

页数：4

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