Triethylsilane-indium(III) chloride system as a radical reagent

被引：78

作者：

Hayashi, N ^{[1
]}

Shibata, I ^{[1
]}

Baba, A ^{[1
]}

机构：

[1] Osaka Univ, Dept Mol Chem Sci & Technol, Ctr Atoms Mol & Ions Control, Grad Sch Engn, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 26期

关键词：

D O I：

10.1021/ol047849v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel generation method of indium hydride (Cl(2)lnH) was found by the transmetalation of InCl3 with Et3SiH. In the intramolecular cyclization of enynes, the previously reported system (NaBH4-InCl3) has a problem of side reactions with the coexistent borane. In contrast, the problem was solved by the presented system, which affords effective hydroindation of alkynes.

引用

页码：4981 / 4983

页数：3

共 25 条

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