SnO2:Eu3+ nanoparticles dispersed in TiO2 matrix:: Improved energy transfer between semiconductor host and Eu3+ ions for the low temperature synthesized samples

被引:84
作者
Ningthoujam, R. S. [1 ]
Sudarsan, V.
Godbole, S. V.
Kienle, L.
Kulshreshtha, S. K.
Tyagi, A. K.
机构
[1] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Div Radiochem, Bombay 400085, Maharashtra, India
[3] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
关键词
D O I
10.1063/1.2731433
中图分类号
O59 [应用物理学];
学科分类号
摘要
SnO2:Eu3+ nanoparticles uniformly dispersed in TiO2 matrix were prepared at 185 degrees C in ethylene glycol. Unlike in SnO2:Eu3+, significant improvement in the exciton mediated energy transfer between SnO2 and Eu3+ ions was observed when SnO2:Eu3+ nanoparticles are dispersed in TiO2 matrix, and this is attributed to effective shielding of surface Eu3+ ions present in SnO2:Eu3+ nanoparticles from the vibrations of stabilizing ligand by TiO2 matrix. Annealing the samples at high temperatures leads to formation of Sn1-xTixO2, without significantly affecting the energy transfer process between Eu3+ ions and semiconductor host. (c) 2007 American Institute of Physics.
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页数:3
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