Fullerene-like structures in CNx particles

被引:13
作者
Radnóczi, G [1 ]
Kovács, GJ [1 ]
Pécz, B [1 ]
Geszti, O [1 ]
Sáfrán, G [1 ]
机构
[1] Hungarian Acad Sci, Res Inst Tech Phys & Mat Sci, H-1121 Budapest, Hungary
关键词
CNx cluster growth; arc evaporation; fullerenlike particles; HREM;
D O I
10.1016/S0042-207X(02)00735-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fullerene-like and amorphous nanoparticles of CNx were prepared by arc evaporation of C in N-2 atmosphere at 10(-2)-10(-3) mbar pressure. The particles were characterised by high-resolution electron microscopy. A surface roughness attributed to CNx shell fragments and a 1-2 nm thick disordered surface layer in fullerene-like particles was found. The formation of the disordered layer and amorphisation at higher nitrogen pressures is thought to be a common origin of nitrogen incorporation and subsequent retardation of the formation of ordered fullerene-like structures. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:185 / 191
页数:7
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