Simple and efficient reduction of aromatic nitro compounds using recyclable polymer-supported formate and magnesium

被引：13

作者：

Abiraj, K ^{[1
]}

Srinivasa, GR ^{[1
]}

Gowda, DC ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2005年 / 58卷 / 02期

关键词：

D O I：

10.1071/CH04220

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aromatic nitro compounds were chemoselectively reduced to the corresponding amines using recyclable polymer-supported formate as a hydrogen donor in the presence of low-cost magnesium powder at room temperature. Use of the immobilized hydrogen donor affords the product amine in excellent yield (90 - 97%) without the need for any chromatographic purification steps. This method was found to be highly facile with selectivity over several other functional groups, such as halogen, alkene, nitrile, carbonyl, ester, amide, methoxy, phenol, and hydroxyl groups.

引用

页码：149 / 151

页数：3

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