High temperature corrosion behavior of iron aluminides containing ternary additions in H2/H2S/H2O mixed gases

被引:21
作者
Kai, W [1 ]
Chu, JP [1 ]
Huang, RT [1 ]
Lee, PY [1 ]
机构
[1] Natl Taiwan Ocean Univ, Inst Mat Engn, Keelung 20224, Taiwan
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 1997年 / 240卷
关键词
high-temperature corrosion; iron aluminides; Cr; Mn; Mo;
D O I
10.1016/S0921-5093(97)00676-X
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The high-temperature corrosion behavior of four iron aluminides containing Fe-18Al (in at.%) and three Fe-18Al-5M alloys (where M was Cr, Mn, or Mo) was studied over the temperature range of 700-900 degrees C in a H-2/H2S/H2O atmosphere. The corrosion kinetics followed the parabolic rate law in all cases, regardless of temperature and alloy composition. The parabolic rate constants decreased with decreasing temperature, and the addition of ternary elements resulted in various decreases in the corrosion rate compared with Fe-18Al. It was found that Mo was effective to improve the corrosion resistance at T equal to or less than 800 degrees C while Cr had a better improvement at 900 degrees C. The scales formed on all iron aluminides were strongly dependent on temperature and ternary addition. (C) 1997 Elsevier Science S.A.
引用
收藏
页码:859 / 870
页数:12
相关论文
共 17 条
[1]  
BAKER H, 1992, ASM HDB, V3, P3
[2]  
Devan J.H., 1989, OXIDATION HIGH TEMPE, P107
[3]   APPLICATION OF WAGNER THEORY TO THE PARABOLIC GROWTH OF OXIDES CONTAINING DIFFERENT KINDS OF DEFECTS .2. DOPED OXIDES [J].
GESMUNDO, F ;
VIANI, F .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (02) :470-479
[4]   A COMPREHENSIVE INVESTIGATION OF THE SULFIDATION BEHAVIOR OF BINARY CO-MO ALLOYS [J].
GLEESON, B ;
DOUGLASS, DL ;
GESMUNDO, F .
OXIDATION OF METALS, 1990, 33 (5-6) :425-455
[5]   OXIDATION OF IRON NICKEL AND COBALT-BASE ALLOYS CONTAINING ALUMINUM [J].
HAGEL, WC .
CORROSION, 1965, 21 (10) :316-&
[6]  
*JANAF, 1986, THERM TABL
[7]   THE HIGH-TEMPERATURE CORROSION BEHAVIOR OF FE-MO-AL ALLOYS IN H2/H2O/H2S MIXED-GAS ENVIRONMENTS [J].
KAI, W ;
DOUGLASS, DL .
OXIDATION OF METALS, 1993, 39 (3-4) :281-316
[8]   The corrosion behavior of Fe-Al alloys in H-2/H2S/H2O atmospheres at 700-900 degrees C [J].
Kai, W ;
Huang, RT .
OXIDATION OF METALS, 1997, 48 (1-2) :59-86
[9]  
KAI W, 1995, P 9 AS PAC CORR CONT
[10]   TRANSPORT-PROPERTIES OF SULFIDE SCALES AND SULFIDATION OF METALS AND ALLOYS [J].
MROWEC, S ;
PRZYBYLSKI, K .
OXIDATION OF METALS, 1985, 23 (3-4) :107-139